Efficient heterogeneous catalytic hydrogenation of acetone to isopropanol on semihollow and porous palladium nanocatalyst.
Identifieur interne : 000757 ( Main/Exploration ); précédent : 000756; suivant : 000758Efficient heterogeneous catalytic hydrogenation of acetone to isopropanol on semihollow and porous palladium nanocatalyst.
Auteurs : RBID : pubmed:24025235Abstract
Highly efficient and remarkable selective acetone conversion to isopropanol has been achieved via a heterogeneous catalytic hydrogenation of acetone by NaBH4 in the presence of semihollow palladium nanoparticles (PdNPs) grown on ITO substrate. PdNPs with high surface defect grown on an indium tin oxide (ITO) surface were prepared via a simple immersion of the substrate into a solution containing K2PdCl6, sodium dodecyl sulphate (SDS), and formic acid for 2 h at room temperature. The sample showed remarkably high heterogeneous catalytic efficiency by producing 99.8% of isopropanol within 6 min using only 0.28 μg of PdNPs on the ITO surface. The present system exhibits heterogenenous catalytic hydrogenation efficiency 1 × 10(6) time higher than using the conventional Raney Ni system.
DOI: 10.1021/am403087m
PubMed: 24025235
Links toward previous steps (curation, corpus...)
Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Efficient heterogeneous catalytic hydrogenation of acetone to isopropanol on semihollow and porous palladium nanocatalyst.</title><author><name sortKey="Balouch, Aamna" uniqKey="Balouch A">Aamna Balouch</name><affiliation wicri:level="1"><nlm:affiliation>Institute of Microengineering and Nanoelectronics, Universiti Kebangsaan Malaysia , 43600 UKM Bangi, Selangor, Malaysia.</nlm:affiliation><country xml:lang="fr">Malaisie</country><wicri:regionArea>Institute of Microengineering and Nanoelectronics, Universiti Kebangsaan Malaysia , 43600 UKM Bangi, Selangor</wicri:regionArea></affiliation></author><author><name sortKey="Ali Umar, Akrajas" uniqKey="Ali Umar A">Akrajas Ali Umar</name></author><author><name sortKey="Shah, Athar Ali" uniqKey="Shah A">Athar Ali Shah</name></author><author><name sortKey="Mat Salleh, Muhamad" uniqKey="Mat Salleh M">Muhamad Mat Salleh</name></author><author><name sortKey="Oyama, Munetaka" uniqKey="Oyama M">Munetaka Oyama</name></author></titleStmt><publicationStmt><date when="2013">2013</date><idno type="doi">10.1021/am403087m</idno><idno type="RBID">pubmed:24025235</idno><idno type="pmid">24025235</idno><idno type="wicri:Area/Main/Corpus">000409</idno><idno type="wicri:Area/Main/Curation">000409</idno><idno type="wicri:Area/Main/Exploration">000757</idno></publicationStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Highly efficient and remarkable selective acetone conversion to isopropanol has been achieved via a heterogeneous catalytic hydrogenation of acetone by NaBH4 in the presence of semihollow palladium nanoparticles (PdNPs) grown on ITO substrate. PdNPs with high surface defect grown on an indium tin oxide (ITO) surface were prepared via a simple immersion of the substrate into a solution containing K2PdCl6, sodium dodecyl sulphate (SDS), and formic acid for 2 h at room temperature. The sample showed remarkably high heterogeneous catalytic efficiency by producing 99.8% of isopropanol within 6 min using only 0.28 μg of PdNPs on the ITO surface. The present system exhibits heterogenenous catalytic hydrogenation efficiency 1 × 10(6) time higher than using the conventional Raney Ni system.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="PubMed-not-MEDLINE"><PMID Version="1">24025235</PMID><DateCreated><Year>2013</Year><Month>10</Month><Day>09</Day></DateCreated><DateCompleted><Year>2014</Year><Month>05</Month><Day>14</Day></DateCompleted><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1944-8252</ISSN><JournalIssue CitedMedium="Internet"><Volume>5</Volume><Issue>19</Issue><PubDate><Year>2013</Year><Month>Oct</Month><Day>9</Day></PubDate></JournalIssue><Title>ACS applied materials & interfaces</Title><ISOAbbreviation>ACS Appl Mater Interfaces</ISOAbbreviation></Journal><ArticleTitle>Efficient heterogeneous catalytic hydrogenation of acetone to isopropanol on semihollow and porous palladium nanocatalyst.</ArticleTitle><Pagination><MedlinePgn>9843-9</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1021/am403087m</ELocationID><Abstract><AbstractText>Highly efficient and remarkable selective acetone conversion to isopropanol has been achieved via a heterogeneous catalytic hydrogenation of acetone by NaBH4 in the presence of semihollow palladium nanoparticles (PdNPs) grown on ITO substrate. PdNPs with high surface defect grown on an indium tin oxide (ITO) surface were prepared via a simple immersion of the substrate into a solution containing K2PdCl6, sodium dodecyl sulphate (SDS), and formic acid for 2 h at room temperature. The sample showed remarkably high heterogeneous catalytic efficiency by producing 99.8% of isopropanol within 6 min using only 0.28 μg of PdNPs on the ITO surface. The present system exhibits heterogenenous catalytic hydrogenation efficiency 1 × 10(6) time higher than using the conventional Raney Ni system.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Balouch</LastName><ForeName>Aamna</ForeName><Initials>A</Initials><Affiliation>Institute of Microengineering and Nanoelectronics, Universiti Kebangsaan Malaysia , 43600 UKM Bangi, Selangor, Malaysia.</Affiliation></Author><Author ValidYN="Y"><LastName>Ali Umar</LastName><ForeName>Akrajas</ForeName><Initials>A</Initials></Author><Author ValidYN="Y"><LastName>Shah</LastName><ForeName>Athar Ali</ForeName><Initials>AA</Initials></Author><Author ValidYN="Y"><LastName>Mat Salleh</LastName><ForeName>Muhamad</ForeName><Initials>M</Initials></Author><Author ValidYN="Y"><LastName>Oyama</LastName><ForeName>Munetaka</ForeName><Initials>M</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType>Journal Article</PublicationType><PublicationType>Research Support, Non-U.S. Gov't</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2013</Year><Month>09</Month><Day>25</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>ACS Appl Mater Interfaces</MedlineTA><NlmUniqueID>101504991</NlmUniqueID><ISSNLinking>1944-8244</ISSNLinking></MedlineJournalInfo></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="aheadofprint"><Year>2013</Year><Month>9</Month><Day>25</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2013</Year><Month>9</Month><Day>13</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2013</Year><Month>9</Month><Day>13</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2013</Year><Month>9</Month><Day>13</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="doi">10.1021/am403087m</ArticleId><ArticleId IdType="pubmed">24025235</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=IndiumV2/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000757 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 000757 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= *** parameter Area/wikiCode missing ***
|area= IndiumV2
|flux= Main
|étape= Exploration
|type= RBID
|clé= pubmed:24025235
|texte= Efficient heterogeneous catalytic hydrogenation of acetone to isopropanol on semihollow and porous palladium nanocatalyst.
}}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Exploration/RBID.i -Sk "pubmed:24025235" \
| HfdSelect -Kh $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd \
| NlmPubMed2Wicri -a IndiumV2
| This area was generated with Dilib version V0.5.76. |  |